Occurrence and fate of polycyclic aromatic hydrocarbons in the coastal surface microlayer   总被引：2，自引：0，他引：2  

Guitart C  García-Flor N  Bayona JM  Albaigés J 《Marine pollution bulletin》2007,54(2):186-194

Polycyclic aromatic hydrocarbons (PAHs) were measured in the coastal sea surface microlayer (SML), the sub-surface waters (SSW) and the overlying atmosphere in order to investigate the influence of the SML on contaminant enrichment and air-sea exchange. Samples were collected at two contrasting locations of the NW Mediterranean, one urban influenced (off Barcelona, Spain) and another comparatively clean (off Banyuls-sur-Mer, France). Statistical data analysis confirmed the accumulation of PAHs in the SML with respect to the SSW (20.3+/-9.1 vs. 13.1+/-10.0 ng L(-1) in the dissolved phase; 709+/-207 vs. 158+/-111 ng g(-1) in the particulate phase). This accumulation was higher at the contaminated location (Barcelona station) compared with the more pristine one, with PAH enrichments 1.5 and 4.5 times higher for the dissolved and particulate phases, respectively, indicating that the enrichment of PAHs in the SML is dominated by particle transport processes.  相似文献   

Is organic matter a source or redox driver or both for arsenic release in groundwater?     

《Physics and Chemistry of the Earth》2013

  相似文献   

Assessment of Urban Source Metal Levels in Influent,Effluent, and Sludge of Two Municipal Biological Nutrient Removal Wastewater Treatment Plants of Bursa,an Industrial City in Turkey     

Nezih Kamil Salihoglu 《洁净——土壤、空气、水》2013,41(2):153-165

Removal of Al, As, Cd, total Cr (Tot. Cr), Cu, Total Fe (Tot. Fe), Mn, Ni, Pb, Sb, Sn, and Zn from urban effluent by wastewater treatment plants (WWTPs) operated under five‐stage Bardenpho® process were investigated and water soluble metals in the dewatered sludge were quantified. Samples were collected from two WWTPs on a weekly basis over an approximately 2.5‐year time span. Tot. Fe and Al were the most abundant, As, Pb, Ni, Cu, and Cd were the least abundant metals in the influents of both WWTPs. Removal efficiencies above 75% were achieved for Tot. Cr, Tot. Fe, Al, and Cu, whereas, no significant removal was observed for As, Cd, Pb, Sb, and Sn. Removal of Tot. Cr, Cu, Tot. Fe, Zn, Al, Mn, and Ni were influenced by influent suspended solids concentrations, and of Tot. Cr, Zn, and Cd were influenced by their initial content in the influent. Zn removal efficiency of biological nutrient removal (BNR) system in this study was higher and Cd removal efficiency was lower than that of conventional activated sludge reported in the literature. No remarkable difference for metals such as Cu, Mn, Ni, and Pb was observed between the removal efficiencies of conventional system and BNR system.  相似文献   

海洋中铁的来源、形态和对初级生产力的限制作用   总被引：6，自引：0，他引：6  

秦延文  张曼平  周革非 《海洋科学进展》1998,(3)

在海洋中,铁和Ｎ、Ｐ等主营养盐一样,也是一种限制浮游植物初级生产力的重要因素。由于铁是一种化学活性较高的元素,所以海水中铁的存在形态、来源及沉降会直接影响其生物可利用性。目前人们一般采用预富集／原子吸收法（ＡＡＳ）或是借助于电分析技术（如催化极谱）来测定海水中的铁。  相似文献   

Comparative Study on Two Methods for Measuring Wave Velocity Change of Crustal Medium Based on Large Volume Airgun Excitation Data     

YE Beng  CAO Wenzhong  HUO Yuanhang  CHEN Ji  LI Xiaobin 《中国地震研究》2019,33(4):584-595

This paper proposes the application of dynamic programming method to calculate the relative change of wave velocities and compares its similarities and differences with the cross-correlation delay estimation method based on interference. The results show that:①the trend of wave velocities obtained by cross-correlation method and dynamic programming method are consistent. Besides,it is considered that the calculated result using cross-correlation delay method is reliable.② Compared with the cross-correlation delay method,the calculated result of the dynamic programming method has a magnifying effect and is more sensitive to small disturbances.③ Under ideal conditions,the wave velocity change trend calculated by P-wave and S-wave phase should be consistent. In addition,the cross-correlation delay method is used to calculate the wave velocity change.Under appropriate conditions,the process of recovering from the suspected wave velocity before the M_L1. 1 earthquake near the airgun source can be observed.  相似文献   

A Comparative Study on the Excitation of Large Volume Airgun Source with Different Combinations in Hutubi, Xinjiang, China     

SU Jinbo  WANG Qiong  CHEN Hao  WEI Yunyun  ZHANG Wenxiu  WANG Haitao 《中国地震研究》2019,33(4):573-583

In order to study the excitation of large-volume airgun source with different combinations in Hutubi, Xinjiang,China,we conducted a targeted experiment. The method of time-frequency analysis is used to study the signals recorded by a seismometer on the shore of the excited pool, and it is concluded that different gun combinations will lead to different frequency of bubble pulse signals. Besides, linear combination method is used to analyze the signal-to-noise ratios of signals excited by different gun combinations which was recorded by seismic stations around the airgun source. In order to improve the signal-to-noise ratios, it is more effective to increase the activation energy (the number of excited guns at the same time) than to stack the excited signals with smaller energy repeatedly.  相似文献   

Regional Scale Seismological Investigation on the Continent Crust Using Airgun Sources——A Perspective Review   总被引：1，自引：1，他引：0  

Wang Weitao  Wang Baoshan  Jiang Shengmiao  Hu Jiupeng  Zhang Yuansheng 《中国地震研究》2018,32(3):315-329

The investigations on the structure and temporal variations of the continent crust have been the long-lasting topics of seismology. The artificial sources play the most important role in these studies for their well-known locations and occur times among all the sources producing elastic waves, so that precise results are obtained. In past decades, we have successfully excited the airgun sources in on-land water bodies such as reservoirs, expanding their applications in marine seismology. Large volume airguns have been used to produce low frequency signals which can travel hundreds of kilometers after stacking, providing a source connecting the exploration seismology and traditional seismology at regional scale. In this review, we introduce the changes through which we turn the airgun into scientific instruments by experiments. We also present the advances on imaging the continental crust structure and monitoring the velocity variations using the highly repeatable signals emitted by airgun sources. The potential applications such as imaging the subsurface of urban areas and high resolution illuminating of mines are proposed and the challenges for further investigations are also discussed.  相似文献   

Reliability Evaluation on Weak Signal Extraction for Airgun Source Surveys     

Wu Anxu  Ye Beng 《中国地震研究》2018,32(2):265-279

Based on the data synthesis simulation and the actual processing of the airgun seismic source signal, three quantitative indicators of signal-to-noise ratio, waveform correlation coefficient and phase offset, are superimposed. We systematically evaluate the functions of the following three stack methods including linearity, phase weighting and S-transform in the extraction of weak signals under strong background noise and quantitatively estimate the reliability of the stack results. Through the comprehensive discussion of the above three methods of stack results, the preliminary comparative analysis believes that the linear stack signal-to-noise ratio is low, but the waveform distortion is minimal; the phase-weighted superimposed signal-to-noise ratio is high and the phase offset is small, but the results of the waveform quality and linear stack are larger than the deviation; the S-transform stack has a relatively higher signal-to-noise ratio and a small loss of waveform amplitude, but there is a certain phase shift phenomenon. It is therefore suggested that linear stack technology should be used when the requirements of both waveform quality and time precision are high. However, the selection of the stack method when the airgun source excitation is limited should be emphasized. If high fidelity is required, the S-transform stack method should be selected; if the required time is high, accuracy can be selected by phase-weighted stack method to achieve reasonable extraction of weak signals.  相似文献   

共和盆地西缘柔起岗地区变质岩系LA-ICP-MS锆石U-Pb年龄 —原岩最大沉积时代及物源研究          下载免费PDF全文

李瑞保  裴先治  杨栓海  王伟峰  魏立勇  孙雨  李飞  刘满年  赵长存  李佐臣  杨高学  陈力子 《地质学报》2016,90(1):93-114

共和盆地西缘原划古元古代金水口岩群中发育一套低级变质的灰色绢云石英片岩、绢云石英岩及黑云石英片岩组合,该套变质岩系原岩沉积时代及变质基底构造属性存在争议。本文对采自青海省兴海县柔起岗地区的两件片岩样品开展了系统的岩石学及LA-ICP-MS锆石 U-Pb年代学研究,对其原岩沉积时代、沉积物源及基底构造亲缘性进行了探讨。结果表明,该套片岩两件样品的碎屑锆石U-Pb年龄谱可明显分为新元古代和古元古代两个主年龄谱以及中元古代的两个次年龄谱,新元古代主年龄谱分别为688-908 Ma和711-841 Ma,峰值年龄为788 Ma和780 Ma,古元古代主年龄谱分别为1871-2174 Ma和1832-2194 Ma,峰值年龄为2140 Ma和2072 Ma,中元古代两个次年龄谱分别为1520-1638 Ma和1271-1276 Ma,峰值年龄为1635 Ma和1275 Ma。片岩最小碎屑锆石年龄值688 Ma限定了其原岩的最大沉积时代。塔洞片岩碎屑锆石U-Pb年龄谱特征表明其碎屑物质来源较为复杂,物源主体来自周邻造山带的西秦岭、东昆仑和柴达木盆地北缘构造带的前寒武纪块体,扬子板块对其沉积物源亦有部分贡献,而华北板块没有对其提供沉积物源。更为重要的是,该套片岩锆石U-Pb年龄谱突出显示新元古代早期的构造-岩浆-热事件年龄信息,而没有华北板块典型的1850 Ma 和2500 Ma左右的特征,结合区域资料认为西秦岭源区基底与东昆仑地块、柴达木盆地北缘、祁连地块等一样表现出扬子板块的构造亲缘性,源区基底固结时代为新元古代早期。  相似文献   

青海锡铁山铅锌矿床硫同位素地球化学研究——深源与海水硫的混合   总被引：5，自引：0，他引：5  

祝新友  王莉娟  朱谷昌  邓吉牛  樊俊昌 《岩石学报》2010,26(3):657-666

锡铁山铅锌矿床发育较为完整的喷流沉积系统,包括管道相、近喷口相、远端沉积相及各种喷流沉积岩,并有后期改造作用形成的脉状铅锌矿体。本文通过喷流沉积系统各部位硫化物硫同位素的分析,不同部位硫化物硫同位素组成不同,且规律性变化。以黄铁矿分析结果为例,网脉状石英钠长岩δ34S=+0.8‰,代表供给系统的硫化物脉2.95‰,非层状矿体4.48‰,层状矿体3.25‰,炭质片岩为+6.26‰,后期改造型铅锌矿脉为+2.93‰。代表管道相的网脉状石英钠长岩黄铁矿具有深源(幔源)的硫同位素组成,而矿体或大理岩上盘炭质片岩具有海水硫来源的特点。矿体的硫介于二者之间,更靠近炭质片岩的硫化物同位素组成,其来源可能更多受海水硫酸盐的制约,即锡铁山矿床硫具有混合来源性质,主要是海水硫酸盐的还原,部分来源于深部卤水的供给。硫的还原方式以生物细菌还原为主。层状矿体中硫同位素组成由早至晚δ34S逐渐降低,表明层状矿体成矿作用过程中,发生了生物成因的H2S的大量加入。  相似文献